• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.
    公开号:SU893127A3
    申请号:SU772532703
    申请日:1977-10-18
    公开日:1981-12-23
    发明作者:Фергюсон Вайт Джеймс；Гарсайд Шоу Вилфрид
    申请人:Дзе Стандарт Ойл Компани (Инофирма)；
    IPC主号:
    专利说明:

    ammonium NH HjAsO and heated for 20 minutes; the color was white. After the addition of 2.5 g of copper acetate, the color changes to light blue. To this mixture, 7v6 g of phosphoric acid H2 | PO4 (solution) was added, and after 10 minutes 2.5 g of hydrazine hydrate was added to give a dark blue solution, which was evaporated to a thick paste, dried overnight at 120 ° C. Comparative Example A. Mo, P ,, j o, f This catalyst is prepared from a portion of the active catalytic one. material prepared as described above. The catalyst is crushed and sieved to a size of 1V30 mesh. Comparative example B. 25., 5 0.45 + 75% (impregnated) This catalyst is prepared by impregnation with a part of a catalytic solution of Norton brand SA-5209 alundum beads; 1/8 (alumina with a low surface) before drying. Comparative example C. 25 (7.5 0.15 Of + + 75 .j (coBMecTHO gelled). This catalyst is prepared by mixing a colloidal aluminum oxide material, C -Loyd A-30, with a portion of the catalytic solution, drying the resulting product and sieving up to a size of 14/30 mesh. Comparative example p 0. 25, Ast, 5 Sirdso + + 75% (mixed together). This catalyst is prepared by mixing fine AInOj Norton BA-Yub with a portion of the catalyst solution and drying the resulting product. Example 1. 25% + 75% AI, (coated). This catalyst is prepared by The coating is coated with an active catalytic material of alundum Norton 5223 balls with a size of 10/30 mesh 1/8, while taking 50 grams of alundum, moistening an alundum of 1.8 cm water and adding 16.7 g of active catalyst in five equal portions. and after each addition, the alund is rolled into glass containers to obtain a solid, uniformly coated catalyst, which consists of a carrier — from an alundum with a continuous, firmly adhered coating of the active catalyst. Example 2. 25%, 0 (jne + 75% alundum (with coating). This catalyst was prepared in the same way, except that g of phosphoric acid was used. The catalyst was coated on alundane in the same manner as described in Example 1. Comparative examples E-T and examples 3-6. The effect of the coating on the type of catalyst ((l, JaQsOf P preparation of methacrylic acid. The catalysts are prepared in the same way using appropriate ratios of ingredients. Each catalyst is calcined for 1 hour at 370 ° C in kO ml / min of air. Portion of particles These catalysts are loaded into a 20 cm fixed bed reactor consisting of a 1.3 cm stainless steel tube equipped with a 0.3 cm axial pocket of a thermocouple, however in examples KN a 0.15 cm thermocouple is used. The reactor is heated to a reaction temperature by current air, and then the starting mixture methacrolein: air: nitrogen: steam is passed over the catalyst at a ratio of 1/5: 7 / 6/8: 7 with an apparent contact time of 2-3 s. The reactor is operated under the reaction conditions and the view is evaluated by collecting and product analysis. The effect of the coating on the type of catalyst M. А5 (55 Pu preparation of methacrylic acid is shown in Table 1. Examples 7–11. A catalyst of the formula 25% + + 75% alundum is prepared in accordance with Example 2 and reacted with methacrolein in the manner described above.The effect of the coating on the type of catalyst 25% P JoD50f +75 alundum in the preparation of methacrylic acid is shown in Table 2.
    Table 1
    table 2
    The catalyst was not fully activated.
    权利要求:
    Claims (1)
    [1]
    1. US patent No. 3761516, CL. C 07 C 57/0 +, published, 1973 (prototype).
    类似技术:
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    同族专利:
    公开号 | 公开日
    ATA709477A|1980-03-15|
    US4110369A|1978-08-29|
    JPS6135976B2|1986-08-15|
    CS199688B2|1980-07-31|
    FR2368460A1|1978-05-19|
    IT1088095B|1985-06-04|
    NO773569L|1978-04-20|
    RO72506A|1980-12-30|
    GB1574997A|1980-09-17|
    JPS5350116A|1978-05-08|
    BE859860A|1978-02-15|
    PT67140A|1977-11-01|
    NL7711376A|1978-04-21|
    AT359045B|1980-10-10|
    PT67140B|1979-03-19|
    IN146482B|1979-06-16|
    DE2746137A1|1978-04-20|
    DD133432A5|1979-01-03|
    ES463325A1|1978-07-16|
    BG40478A3|1986-12-15|
    CA1116182A|1982-01-12|
    BR7706927A|1978-06-27|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    BE789241A|1971-09-28|1973-03-26|Halcon International Inc|Catalyst for the oxidation of unsaturated aldehydes|
    US4077912A|1972-10-12|1978-03-07|Standard Oil Company|Catalysts useful for exothermic reactions|
    JPS5232445B2|1973-07-04|1977-08-22|
    JPS5037717A|1973-08-15|1975-04-08|
    JPS5529061B2|1973-08-16|1980-07-31|
    US3956377A|1974-06-17|1976-05-11|The Standard Oil Company |Production of unsaturated acids from the corresponding aldehydes|
    US3939096A|1974-09-24|1976-02-17|Celanese Corporation|Supported catalyst for acrolein oxidation|US4271040A|1978-12-26|1981-06-02|Halcon Research And Development Corp.|Catalyst and process for producing methacrylic acid|
    US4280928A|1979-10-12|1981-07-28|Rohm And Haas Company|Catalyst compositions and their use for the preparation of methacrolein|
    US4473707A|1981-01-16|1984-09-25|The Standard Oil Company|Oxidative dehydrogenation of carboxylic acids with mixed metal phosphorus oxide coated catalysts|
    US4364856A|1981-01-16|1982-12-21|The Standard Oil Company|Mixed metal phosphorus oxide coated catalysts for the oxidative dehydrogenation of carboxylic acids|
    JPS58112050A|1981-12-24|1983-07-04|Ube Ind Ltd|Preparation of catalyst for production of methacrylic acid|
    US4410448A|1981-12-28|1983-10-18|The Standard Oil Company|Method for controlling the change in the crush strength of a catalyst particle during finishing calcination|
    CN103861640B|2014-03-13|2015-07-29|万华化学集团股份有限公司|A kind of heteropolyacid catalyst and preparation method thereof|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US05/733,736|US4110369A|1976-10-19|1976-10-19|Process for the preparation of unsaturated acids from unsaturated aldehydes|
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